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Carbon-Based Energy Systems > CO2 Capture
Novel Ionic Liquids for Pre-Combustion CO2 Capture

Start Date: July 2012
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Investigators

Joan F. Brennecke1, Brandon L. Ashfeld2, Edward J. Maginn1, William F. Schneider1, 2 and Mark A. Stadtherr1, 1Department of Chemical and Biomolecular Engineering, 2Department of Chemistry and Biochemistry, University of Notre Dame

Annual Reports

Publications

  • T. B. Lee, S. Oh, T. R. Gohndrone, O. Morales-Collazo, S. Seo, J. F. Brennecke, and W. F. Schneider, "CO2 Chemistry of Phenolate-Based Ionic Liquids," J. Phys. Chem. B 2016, 120, 1509–1517.
  • Bo Hong, Luke D. Simoni, Joshua E. Bennett, Joan F. Brennecke, and Mark A. Stadtherr. "Simultaneous Process and Material Design for Aprotic N-Heterocyclic Anion Ionic Liquids in Post-Combustion CO2 Capture, submitted for publication (2016).
  • Ramesh Singh, Eliseo Marin-Rimoldi and Edward J. Maginn, "A Monte Carlo Simulation Study To Predict the Solubility of Carbon Dioxide, Hydrogen, and Their Mixture in the Ionic Liquids 1‐Alkyl-3- methylimidazolium bis(trifluoromethanesulfonyl)amide ([Cnmim+][Tf2N−], n = 4, 6)", Industrial and Engineering Chemistry Research, 2015, 54, 4385-4395.
  • Samir Budhathoki, Jindal K. Shah and Edward J. Maginn, "Molecular Simulation Study of the Solubility, Diffusivity and Permselectivity of Pure and Binary Mixtures of CO2 and CH4 in the Ionic Liquid 1-n-Butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide", Industrial and Engineering Chemistry Research, 2015, 54, 8821–8828
  • Haugen, K. C.; Rodriguez, K. X.; Chavannavar, A. P.; Oliver, A. P.; Ashfeld, B. L. "Phosphine- Mediated Addition of 1,2-Dicarbonyls to Diazenes: An Umpolung Approach toward N-Acyl Hydrazone Synthesis." Tetrahedron Lett. 2015, 56 (23), 3527-3530. DOI: doi:10.1016/j.tetlet.2015.01.030.
  • Thomas R. Gohndrone, Tae Bum Lee, M. Aruni DeSilva, Mauricio Quiroz-Guzman, William F. Schneider and Joan F. Brennecke, "Competing Reactions of CO2 with Cations and Anions in Azolide Ionic Liquids," ChemSusChem, 2014, 7(7), 1970-1975.
  • Samuel Seo, Mauricio Quiroz-Guzman, Aruni DeSilva, Tae Bum Lee, Yong Huang, Brett F. Goodrich, William F. Schneider, and Joan F. Brennecke, "Chemically Tunable Ionic Liquids with Aprotic Heterocyclic Anions (AHAs) for CO2 Capture," J. Phys. Chem. B, 2014, 118, p. 5740-5751.
  • Samuel Seo, M. Aruni DeSilva and Joan F. Brennecke, "Physical Properties and CO2 Reaction Pathway of 1-Ethyl-3-Methylimidazolium Ionic Liquids with Aprotic Heterocyclic Anions," J. Phys. Chem. B., 2014, 118 (51), pp 14870-14879.
  • Chavannavar, A. P.; Oliver, A. G.; Ashfeld, B. L. "An Umpolung Approach toward N-Aryl Nitrone Construction: Phosphine-Mediated Addition of 1,2-Dicarbonyls to Nitroso Electrophiles." Chem. Commun. 2014, 50 (74), 10853-10856.
  • L. M. Fleury, E. E. Wilson, M. Vogt, T. J. Fan, A. G. Oliver, B. L. Ashfeld, "An Amine-Free Approach Toward N-Toluenesulfonyl Amidine Construction: A Phosphite-Mediated Beckmann-Like Ligation of Oximes and Azides." Angew. Chem. Int. Ed. 2013, 52 (44), 11589-11593.
  • M. Vogt, C. Wu, A. G. Oliver, W. F. Schneider, B. L. Ashfeld, "Site Specific Carboxylation of Abnormal Anionic N-Heterocyclic Dicarbenes with CO2." Chem. Commun. 2013, 49 (98), 11527-11529.
  • Monika Vogt, Joshua E. Bennett, Yong Huang, Chao Wu, William F. Schneider, Joan F. Brennecke and Brandon L. Ashfeld, "Solid State Covalent Capture of CO2 Using N-Heterocyclic Carbenes," Chemistry – A European Journal, 2013, 19(34), 11134-11138.

Presentations

  • Brandon L. Ashfeld. "From Carbonto Cancer: TheImpact of Reaction Developmenton Natural Products and Designed Materials Synthesis." Department of Chemistry and Biochemistry, Hope College, Holland, MI. November 6, 2015.
  • Brandon L. Ashfeld. "From Carbonto Cancer: TheImpact of Reaction Developmenton Natural Products and Designed Materials Synthesis." Department of Chemistry and Biochemistry, Calvin College, Grand Rapids, MI. November 5, 2015.
  • T. B. Lee, S. Seo, Q. Sheridan, T. R. Gohndrone, G. A. Bonilla, E. Maginn, J. F. Brennecke, W. F. Schneider, "CO2 Capture Chemistry of Azolide-based Ionic Liquids: Interplay between CO2, Ions, and Water" 250th ACS National Meeting and Exposition, August 16-20, 2015, Boston, MA
  • "Redox Phosphorus(V/III)-Mediated C–N and C–C Bond Formations." Justin D. Vail, Kevin X. Rodriguez, Erin E. Wilson, Jennifer L. Meloche, Antonio J. Lepore, Kaitlyn Eckert and Brandon L. Ashfeld. 62nd Organic Reactions and Process Gordon Research Conference, Bates College, Lewiston, ME. July 19-24, 2015 (poster presentation).
  • T. B. Lee, T. R. Gohndrone, S. Seo, S. M. Oh, J. F. Brennecke, W. F. Schneider, "CO2 capture chemistry of task-specific ionic liquids: Interplay between CO2, cation, and anion" 6th International Congress of Ionic Liquids, June 16-20, 2015, Jeju, Korea
  • Joan F. Brennecke, Samuel Parr Lecture, Carbon Capture with Ionic Liquids, Department of Chemical Engineering, University of Illinois at Urbana-Champaign, May 7, 2015.
  • Joan F. Brennecke, "Using Ionic Liquids for Post-Combustion Carbon Capture," Department of Chemical Engineering, University of Washington, April 27, 2015.
  • W. F. Schneider, "Design Principles for Reversible CO2 Chemistries," Rice University, Department of Chemical and Biomolecular Engineering, Houston, Texas, April 23, 2015.
  • W. F. Schneider, "Design Principles for Reversible CO2 Chemistries," American Chemical Society National Meeting, Denver, Colorado, March 25, 2015.
  • Brandon L. Ashfeld. "Nitrene and Carbene Surrogates: New Methods in C–N and C–C Bond Formation for Heterocycle Construction." 249th American Chemical Society National Meeting and Symposium, Denver, CO. March 25, 2015.
  • Edward J. Maginn, "Combining Molecular Simulations and Advanced Analysis Tools to Enable Rapid and Reliable Thermophysical Property Prediction", International Workshop on Molecular Modeling and Simulation: Science, Engineering and Industrial Applications, DECHEMA House, Frankfurt Main, Germany, March 24, 2015.
  • Edward J. Maginn, "Using Molecular Simulation to Understand and Control the Thermodynamic and Transport Properties of Ionic Liquids", Department of Chemical Engineering colloquium, University of South Carolina, Columbia, SC. March 5, 2015.
  • Edward J. Maginn, "Predicting the Thermodynamic and Transport Properties of Ionic Liquids via Molecular Simulation", Department of Chemical and Biomolecular Engineering colloquium, University of California at Berkeley, Berkeley, CA, Feb. 25, 2015.
  • Joan F. Brennecke, Symposium in Honor of Charlie Liotta, "Reaction Chemistry of Ionic Liquids with CO2 for Post-Combustion Capture," Department of Chemisty, Georgia Institute of Technology, February 26, 2015.
  • Joan F. Brennecke, Institute for Materials Research Distinguished Lecture Series, "Ionic Liquids for Post-Combustion CO2 Capture," Ohio State University, February 18, 2015.
  • Joan F. Brennecke, "Ionic Liquids for Post-Combustion CO2 Capture," Andlinger Center for Energy and the Environment, Princeton University, January 16, 2015.
  • B. Hong, J. E. Bennett, J. F. Brennecke, and M. A. Stadtherr, "Chemically-Complexing Ionic Liquids for Pre-Combustion CO2 Capture: Design of Chemical Properties," AIChE Annual Meeting, Atlanta, GA, November 16-21, 2014.
  • Joan F. Brennecke, Global Climate and Energy Project (GCEP) Distinguished Lectures, "CO2 Removal with Ionic Liquids," Bank of America August 1, 2014; Exxon-Mobil August 4, 2014; GE August 22, 2014; DuPont August 25, 2014.
  • Joan F. Brennecke, "Ionic Liquids for CO2 Capture: Chemisty, Cosolvents and Ionicity," Gordon Research Conference," August 17-22, 2014.
  • Brandon L. Ashfeld. "Nitrene and Carbene Surrogates: New Methods in C–N and C–C Bond Formation for Heterocycle Construction." 248th American Chemical Society National Meeting and Symposium, San Francisco, CA. August 16, 2014.
  • Joan F. Brennecke, The Fred Kavli Innovations in Chemistry Lecture, "How Ionic Liquids Can Contribute to Global Stewardship," ACS National Meeting, San Francisco, CA, August 11, 2014.
  • Samuel Seo and Joan F. Brennecke, Keynote Speaker, "The Effect of Additives and Cation-Anion Association on CO2 Uptake by AHA Ionic Liquids," ILSEPT-2nd International Conference on Ionic Liquids in Separation and Purification Technology, Toronto, Canada, June 29-July 2, 2014.
  • Thomas Gohndrone and Joan F. Brennecke, "Temperature and Pressure Effect on the Capture of CO2 with Phosphonium Based Ionic Liquids," poster presentation, ILSEPT-2nd International Conference on Ionic Liquids in Separation and Purification Technology, Toronto, Canada, June 29-July 2, 2014.
  • Brandon L. Ashfeld. "Nitrene and Carbene Surrogates: New Methods in C–N and C–C Bond Formation for Heterocycle Construction." 51st Gordon Research Conference on Heterocyclic Compounds, Salve Regina University, Newport, RI. June 17, 2014.
  • Joan F. Brennecke, "Thermodynamics of Mixtures of Ionic Liquids and Gases," US Poland Workshop on the Thermodynamics of Complex Fluids and Interfaces," Warsaw, Poland, June 13, 2014.
  • Joan F. Brennecke, Katz Award Lecture and Levich Institute Lecture, "Designing Ionic Liquids for CO2 Capture" and "Tuning the Properties of Ionic Liquids and Ionic Liquid Mixtures," City College of New York, April 28 and 29, 2014.
  • Joan F. Brennecke, Ashton Cary Lectures, "Using Ionic Liquids for Energy Applications" and "Effect of Cation, Water and Other Additives on AHA Ionic Liquids for CO2 Capture," Georgia Institute of Technology, April 23 and 24, 2014.
  • Joan F. Brennecke, "Ionic Liquids in Industrial and Engineering Chemistry," E. V. Murphree Award address, 247th National Meeting of the American Chemical Society, Dallas, TX, March 19, 2014.
  • Joan F. Brennecke, "Designing Ionic Liquids for CO2 Capture," Texas Tech University, January 24, 2014.
  • Joan F. Brennecke, "Reaction Chemistry of Ionic Liquids for CO2 Capture," Colorado School of Mines, January 17, 2014.
  • Ramesh Singh and Edward J. Maginn, "The Solubility of Carbon Dioxide, Hydrogen and their Mixture in the Ionic Liquids 1-alkyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide ([C6mim+][Tf2N- ])", AIChE Annual Meeting, San Francisco, CA, Nov. 2013.
  • Joshua Bennett, Aruni DeSilva and Joan F. Brennecke, "Molar Volume Dependence of N2 Solubility in Ionic Liquids," AIChE Meeting, San Francisco, CA, Nov. 3-8, 2013.
  • Joan F. Brennecke, plenary lecture, "Ionic Liquids for CO2 Capture," 50 Years of Post Graduate Education in Chemical Engineering in Brazil, Federal University of Rio de Janeiro, October 24, 2013.
  • Brandon L. Ashfeld. "Chemoselective Nucleophilic Substitution Strategies Toward Natural Products and Designed Materials." University of Notre Dame, Notre Dame, IN. October 23, 2013.
  • Edward J. Maginn, "Developing New Materials for Energy and Environmental Applications via Molecular Simulation", Department of Chemical and Biological Engineering, Colorado School of Mines, Oct. 4, 2013.
  • Brandon L. Ashfeld. "Novel Diarylheptanoids for the Treatment of Glioblastoma Multiforme."Concepts to Clinic Meeting, Riley Hospital Children's Clinical Research Center, Indianapolis, IN. September 20, 2013.
  • Brandon L. Ashfeld. "Harnessing Masked Electrophilicity and Nucleophilicity: Alternative Strategies for Selective C–C and C–N Bond Formations." Young Academic Investigators Award Symposium, 246th American Chemical Society National Meeting and Exposition, Indianapolis, IN. September 9, 2013.
  • Joan F. Brennecke, Thomas R. Gohndrone, Mauricio Quiroz-Guzman, and M. Aruni DeSilva, "Reaction Chemistry of Phosphonium and Ammonium Ionic Liquids with AHA Anions for CO2 Capture," American Chemical Society, Indianapolis, IN, Sept. 10, 2013.
  • Monika Vogt, and Brandon L. Ashfeld "Carbon Dioxide Separation Using N-Heterocyclic Ionic Liquids and Carbenes." 5th Annual Chicago Organic Symposium. University of Notre Dame, Notre Dame, IN (Poster Presentation). July 12, 2013.
  • "New Methods in Heterocycle Construction: Natural Product and Designed Material Syntheses." Catherine A. Campos, Joseph B. Gianino, Lauren M. Fleury, Antonio J. Lepore, and Brandon L. Ashfeld. 49th Gordon Research Conference on Heterocyclic Compounds, Salve Regina University, Newport, RI. June 16-21, 2013 (poster presentation).
  • Brandon L. Ashfeld. "Maximizing Chemoselectivity and Convergency in the Strategic Assembly of Biologically Active Natural Products." University of Illinois at Chicago, Chicago, IL. May 31, 2013.
  • Brandon L. Ashfeld. "Chemoselective Nucleophilic Substitution Strategies Toward Natural Products and Designed Materials." Northwestern University, Evanston, IL. May 30, 2013.
  • Brandon L. Ashfeld. "Exploiting Unconventional Carbonyl Reactivity for Natural Products and Designed Materials Synthesis." Columbia University, New York, NY. April 24, 2013.
  • Brandon L. Ashfeld. "New Strategies in Chemoselective Carbonyl Functionalization." New York University, New York, NY. April 23, 2013.
  • Thomas R. Gohndrone, Burcu E. Gurkan, Mauricio Quiroz-Guzman, M. Aruni DeSilva, Joan F. Brennecke, "Reaction Kinetics and Mechanism Study: Reaction of Phosphonium Based Amine- Functionalized Ionic Liquids with CO2," 5th Congress on Ionic Liquids, Algarve, Portugal, April 21-25, 2013
  • M. Aruni DeSilva, Samuel Seo, Chaojun Shi, Marjorie Massel and Joan F. Brennecke, "Investigation of Reactivity of Imidazolium Based Aprotic Heterocyclic Anion (AHA) Ionic Liquids Using," (poster and 'flash' presentation), 5th Congress on Ionic Liquids, Algarve, Portugal, April 21-25, 2013.
  • Mauricio Quiroz-Guzman, M. Aruni DeSilva and Joan F.Brennecke, "Ionic liquids with Aprotic Heterocyclic Anions and their reactivity with water and CO2," (poster presentation), 5th Congress on Ionic Liquids, Algarve, Portugal, April 21-25, 2013.
  • Brandon L. Ashfeld. "Maximizing Chemoselectivity and Convergency in the Strategic Assembly of Biologically Active Natural Products." Massachusetts Institute of Technology, Cambridge, MA. April 11, 2013.
  • Brandon L. Ashfeld. "How New Synthetic Methods Enable the Design of Brain and Nervous System Cancer Chemotherapies." Interdisciplinary Science Seminar, SCPP 23100. University of Notre Dame, Notre Dame, IN. April 2, 2013.
Updated July 2016
 

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