Global Climate & Energy Project
HydrogenHydrogen Effects on Climate, Stratospheric Ozone, and Air Pollution
Start Date: January 2004
Mark Z. Jacobson, Civil and Environmental Engineering, David M. Golden, Mechanical Engineering, Stanford University
This project studies the potential effects on climate, stratospheric ozone, and air pollution of converting vehicle fuel and electric power sources, in the U.S. and worldwide, from fossil fuels to hydrogen fuel cells.
Changes in technology have environmental implications that must be studied and examined prior to wide-scale adoption. Previous studies and models have not examined the climate response of a transition to hydrogen, the effect of hydrogen on atmospheric aerosols, nor the effect of using wind, coal, and/or natural gas to generate hydrogen. As such, a significant gap in our understanding of the effects of switching to hydrogen still exists. The purpose of this project is to try to fill some of this void with a numerical model that replaces current and future fossil fuels emissions with hydrogen-related emissions in a high-resolution emission inventory. The model then treats gases, aerosols, meteorology, and radiation simultaneously over a three-dimensional global grid that nests down to the urban scale.Background
About 90% of current H2 emissions originate from oxidation of methane, oxidation of nonmethane hydrocarbons, photolysis of formaldehyde (which originates from methane and isoprene), fossil-fuel combustion (particularly automobiles), and biomass burning. The remaining 10% originates from natural sources. The major losses of hydrogen are dry deposition to soils and oceans, and the chemical reaction, H2 + OH -> H2O + H (e.g., Schmidt, 1974).
One effect of hydrogen in the stratosphere is that it increases water vapor in the ozone. H2O emitted near the surface does not readily penetrate to the stratosphere, but H2 can penetrate readily into the stratosphere, where it can form H2O by the reaction H2 + OH. This is one of the few sources of water in the stratosphere (e.g., Khalil and Rasmussen, 1990; Dessler et al., 1994; Hurst et al., 1999). Increased water in the stratosphere may increase the occurrence and size of Polar Stratospheric Clouds and stratospheric aerosols, both of which enhance stratospheric ozone reduction in the presence of chlorinated and brominated compounds. This issue will be examined as part of this project.
One mechanism by which increases in H2 may enhance global warming is through a series of reactions that would produce O3. In the troposphere, the loss of OH from H2 + OH would appear beneficial at first since OH is the chemical primarily responsible for breaking down organic gases, which generate ozone in photochemical smog. However, the H created from the same reaction instantaneously converts to HO2 by H + O2 + M -> HO2 + M. HO2 forms ozone in the troposphere by NO + HO2 -> NO2 + OH, followed by NO2 + hv -> NO + O, followed by O + O2 + M -> O3 + M. Since O3 is a greenhouse gas, the increase in H2 may slightly increase near-surface global warming. This mechanism of O3 formation is less important in the stratosphere due to the lesser quantity of NO in the stratosphere than in the troposphere. Another chemical effect of H2 is that its reaction, H2 + OH -> H2O + H, reduces the rate of the reaction CH4 + OH -> CH3 + H2O because both reactions compete for a limited amount of OH. As a result, the lifetime of methane, CH4, a greenhouse gas, increases.Activities
(A) Identify the scenarios to consider and all possible changes in emissions associated with each.
(B) To simulate the scenarios defined under Task A, design computer model experiments, run test simulations, and compare results against a large measurement database. Some model improvement will be undertaken.
(C) Run pairs of simulations for each scenario described under Task A. For each pair, run both a baseline simulation representing current fuel use and a sensitivity simulation representing hydrogen fuel use, where hydrogen is generated from difference sources.Approach
For the study, data from emission inventories of vehicles and electric power plants will be replaced with those resulting from hydrogen generation and hydrogen fuel cell use. Base case model predictions will be evaluated against an array of gas, aerosol, and meteorological measurements. Sensitivity studies, in which vehicles and electric power plants are switched to hydrogen, will be analyzed in terms of their resulting effects on climate, stratospheric ozone, and air pollution. The outcome of this study will be a comprehensive assessment of the potential effects on the atmosphere of converting vehicle and electric power sources in the U.S. and worldwide to hydrogen.
Figure 1: Schematic of Model Approach
1. Dessler, A.E., E.M.
Weinstock, E.J. Hintsa, J.G. Anderson, C.R. Webster, R.D. May, J.W.
Elkins, and G.S. Dutton, An examination of the total hydrogen budget of
the lower stratosphere, Geophys.Res. Lett., 21, 2563-2566, 1994.