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Electrochemistry and Electric Grid > Electrocatalysis
Designing Metal Catalysts for Electrochemical Conversion of CO2 and CO to Fuels and Chemicals
Start Date: September 2013
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Investigators

Thomas F. Jaramillo, Department of Chemical Engineering, Stanford University; Jens K. Nørskov, Departments of Chemical Engineering, Stanford University, and of Photon Science, SLAC National Accelerator Laboratory; and Anders Nilsson, Department of Photon Science, SLAC National Accelerator Laboratory

Publications

  • Hansen, H.A.; Shi, C.; Lausche, A.C.; Peterson, A.A.; Nørskov, J. K., "Bifunctional alloys for the electroreduction of CO2 and CO," Phys. Chem. Chem. Phys. 2016, 18, 9194-9201. DOI: 10.1039/C5CP07717F
  • Siahrostami, S.; Tsai, C.; Karamad, M.; Koitz, R.; Garcia-Melchor, M.; Bajdich, M.; Vojvodic, A.; Abild-Pedersen, F.; Nørskov, J. K., "Two-dimensional Materials as Catalysts for Future Energy Conversion," Submitted, 2016.
  • Hong, X.; Chan, K.; Tsai, C.; Nørskov, J. K., "How doped MoS2 breaks transition-metal scaling relations for CO2 electrochemical reduction," Submitted, 2016.
  • Karamad, M.; Shi, C.; Chan, K.; Nørskov, J. K., "Catalyst Screening for the Electrochemical Reduction of CO," In Preparation, 2016.
  • Roberts, F.S.; Kuhl, K.P.; Nilsson, A., "Electroreduction of Carbon Monoxide Over a Copper Nanocube Catalyst: Surface Structure and pH Dependence on Selectivity," ChemCatChem, 2016, 8, 1119-1124. DOI: 10.1002/cctc.201501189
  • Eilert, A.; Roberts, F.S.; Friebel, D.; Nilsson, A., "Formation of Copper Catalysts for CO2 Reduction with High Ethylene/Methane Product Ratio Investigated with In Situ X-ray Absorption Spectroscopy," J. Phys. Chem. Lett., 2016, 7, 1466-1470. DOI: 10.1021/acs.jpclett.6b00367
  • Abram, D. N.; Hatsukade, T.; Hahn, C.; Hansen, H. A.; Shi, C.; Kuhl, K. P.; Cave, E. R.; Feaster, J. T.; Jaramillo, T. F., "Synergistic Electrocatalytic CO2 Reduction Properties of PtIn Alloy Thin Films," In Preparation, 2016.
  • Feaster, J.T.; Shi, C.; Cave, E.R.; Hatsukade, T.; Abram D.N.; Hahn, C.; Kuhl, K.P.; Nørskov, J. K.,; Jaramillo, T.F., "Understanding Selectivity to Carbon Monoxide and Formic Acid via the Electrochemical Reduction of Carbon Dioxide on Sn Electrodes," In Preparation, 2016.
  • "Karamad, M.; Hansen, H. A.; Rossmeisl, J.; Nørskov, J. K., "Mechanistic Pathway in the Electrochemical Reduction of CO2 on RuO2," ACS Catalysis. 2015."
  • Roberts, F.S.; Kuhl, K.P.; Nilsson, A., "High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts," Angew. Chem. Int. Ed. 2015, 127, 5268. DOI: 10.1002/ange.201412214
  • Hahn, C.; Abram, D. N.; Hansen, H. A.; Hatsukade, T.; Jackson, A.; Johnson, N. C.; Hellstern, T. R.; Kuhl, K. P.; Cave, E. R.; Feaster, J. T.; Jaramillo, T. F., "Synthesis of Thin Film AuPd Alloys and their Investigation for Electrocatalytic CO2 Reduction," J. Mater. Chem. A., 2015, 3, 20185-20194. DOI: 10.1039/C5T A04863J
  • K. Chan, C. Tsai, H.A. Hansen, J.K. Nørskov, ChemCatChem, "Molybdenum Sulfides and Selenides as Possible Electrocatalysts for CO2 Reduction", Accepted.
  • T. Hatsukade, K.P. Kuhl, E.R. Cave, D.N. Abram, T.F. Jaramillo, "Insights into the Electrocatalytic Reduction of CO2 on Metallic Silver Surfaces", Submitted.

Presentations

  • Nørskov, J.K., A Theory of transition metal Heterogeneous Catalysis, CHAINS 2015: Chemistry Matters for the Future, Veldhoven, The Netherlands, December, 2015.
  • Nilsson, A. X-ray Studies of Catalysis in Artificial Photosynthesis, Pacific Chemical Meeting, Honolulu, HI, December 2015.
  • Jaramillo, T.F. Electrocatalytic CO2 reduction to fuels and chemicals: Insights into transition metal surfaces, Pacifichem: The International Chemical Congress of Pacific Basin Societies, Honolulu, HI, December 2015.
  • Nørskov, J.K., A Theory of transition metal Heterogeneous Catalysis, AIChE Annual Meeting, Salt Lake City, UT, November, 2015.
  • Hatsukade, T., Hahn, C., Abram, D.N., Hansen, H.A., Shi, C., Karamad, M., Cave, E.R., Feaster, J.T., Nørskov, J.K., and Jaramillo, T.F., Theory-Guided Screening of Binary Alloy Thin Films for Electrochemical Reduction of Carbon Dioxide, AIChE Annual Meeting, Salt Lake City, UT, November, 2015.
  • Feaster, J.T., Fleischman, S.D., Davis, R., Mehta, A., Jaramillo, T.F., Utilizing Grazing Incidence XAS to Investigate Operando CO2 Reduction on Au Electrodes, AIChE Annual Meeting, Salt Lake City, UT, November, 2015.
  • Karamad, M. and Nørskov, J.K., Computational Catalysis Design for Fuel Synthesis, AIChE Annual Meeting, Salt Lake City, UT, November, 2015.
  • Jaramillo, T.F. Generating fuels from sunlight: Catalyst design, development, and integration into devices. Netherlands Center for Multiscale Catalytic Energy Conversion (MCEC) School, Driebergen, Netherlands, October 2015.
  • Jaramillo, T.F. Developing Sustainable Pathways to Fuels and Chemicals. Energy Seminar, Stanford University, Stanford, CA, September 2015.
  • Jaramillo, T.F. Developing a Sustainable Pathway to Fuels and Chemicals. Energy@SLAC&Stanford Conference 2015, Stanford Graduate Summer Institute (SGSI), Stanford University, Stanford, CA. September 2015.
  • Operando X-ray Studies of Electrocatalysis, Photocatalysis Workshop at EMPA, Zurich, August 2015.
  • Nilsson, A. Chemical Energy Transformation at Interfaces, RACIRI summershool, Rugen Island, Germany, August 2015.
  • Jaramillo, T.F. Energy Transformations: Designing and developing electrocatalysts and photoelectrodes, SUNCAT Summer Institute 2015, Stanford University, Stanford, CA, August 2015.
  • Jaramillo, T.F. Producing Renewable Fuels and Chemicals from CO2 and H2O, Stanford Energy 3.0, Stanford University, Stanford, CA, May 2015.
  • Nørskov, J.K., Zhang Dayu Lecture - A Theory of transition metal Heterogeneous Catalysis, Zhang Dayu Lectureship, Dalian Institute of Chemical Physics, Chinese Academy of Sciences Dalian, China, May, 2015.
  • Roberts, F.S., Kuhl, K.P. Nilsson, A., Electrochemical Mass Spectrometry for Carbon Dioxide Reduction, 1st International Solar Fuels Conference, Uppsala, Sweden, April 2015
  • Nørskov, J.K., Dodge Series Lecture - A predictive theory of transition metal surface catalysis, Yale University, Department of Chemical & Environmental Engineering, New Haven, April, 2015.
  • Jaramillo, T.F. Developing New Pathways for the Sustainable Production of Fuels and Chemicals, University of Puerto Rico, Cayey, PR, April 2015.
  • Jaramillo, T.F. Developing New Pathways for the Sustainable Production of Fuels and Chemicals, University of Puerto Rico, Río Piedras, PR, Department of Chemistry, April 2015.
  • Jaramillo, T.F. Developing New Pathways for the Sustainable Production of Fuels and Chemicals, University of Puerto Rico, Mayagüez, Department of Chemical Engineering, April 2015.
  • Hahn, C., Abram, D.N., Hansen, H.A., Shi, C., Hatsukade, T., Kuhl, K.P., Cave, E.R., Feaster, J.T., Nilsson, A., Nörskov, J.K., Jaramillo, T.F., Screening of Binary Alloy Thin Films for Electrochemical CO2 Reduction, Materials Research Society Spring Meeting and Exhibit, San Francisco, CA, April 2015.
  • Jaramillo, T.F. Developing Sustainable Routes for the Production of Fuels and Chemicals, Massachusetts Institute of Technology (MIT), Department of Chemical Engineering, Cambridge, MA, April 2015.
  • Jaramillo, T.F. Trends in transition metal surfaces for the electrocatalytic reduction of CO2 to fuels and chemicals, Third Biennial Carbon Dioxide Workshop, Princeton University, Princeton, NJ, March 2015.
  • Nørskov, J.K., Irving Langmuir prize Lecture – A predictive theory of transition metal surface catalysis, APS March Meeting, San Antonio, TX, March, 2015.
  • Nilsson, A. Spectroscopy for Catalysis with LCLS II, LCLS II Chemistry Workshop, SLAC/Stanford, February 2015.
  • Nørskov, J.K., Electrochemical CO2 Reduction: Theoretical Investigations, MURI (Multi-University Research Initiative) 2014 Review of the project Novel Catalytic Mechanisms for the Chemical Reduction of Carbon Dioxide to Energy-Dense Liquids, La Jolla, CA, January, 2015.
  • Jaramillo, T.F. Long-Range Vision for Renewable Fuels in the Global Energy System, Global Climate Energy Project (GCEP) Roundtable 2015: Long-Range Vision for Renewable Fuels in the Global Energy System, Los Altos, CA, January 2015.
  • Jaramillo, T.F. Sustainable Production of Fuels and Chemicals, Global Climate Energy Project (GCEP) Roundtable 2015: Long-Range Vision for Renewable Fuels in the Global Energy System, Los Altos, CA, January 2015.

Updated July 2015

 

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