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Advanced Materials and Catalysts
Electrocatalysis with Discrete Transition Metal Complexes
- McCrory, C. C. L., X. Ottenwaelder, T. D. P. Stack, C. E. D Chidsey. “Kinetic and mechanistic studies of the electrocatalytic reduction of O2 to H2O with mononuclear Cu complexes of substituted 1,10-phenanthrolines.” Journal of Physical Chemistry A, 111, pp. 12641-12650, doi:10.1021/jp076106z (2007).
- Conley, N. R.; Labois, L.A.; Pearson, D.M.; McCrory, C.; Waymouth, R.M. “Aerobic Alcohol Oxidation with Cationic Palladium Complexes: Insights into Catalyst Design and Decomposition”, Organometallics 2007, 26, 5447-5453.
The Electron Economy: Oxidation Catalysis for Energy Management
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Pearson, D. M., N. R. Conley, and R. M. Waymouth. “Oxidatively resistant ligands for palladium-catalyzed aerobic alcohol oxidation,” Organometallics, 30, 1445, doi:10.1021/om101037k (2011).
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Painter, R. M., D. M. Pearson, and R. M. Waymouth, “Selective catalytic oxidation of glycerol to dihydroxyacetone,” Angew. Chem., Int. Ed., 49, 9456-9459 doi:10.1002/anie.201004063 (2010).
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Pearson, D. M., N. R. Conley, and R. M. Waymouth. “Palladium-catalyzed carbonylation of diols to cyclic carbonates,” Adv. Synth. Cat. (submitted for publication, 2011).
- McCrory, C. C. L., A. Devadoss, X. Ottenwaelder, R. D. Lowe, T. D. P. Stack, and C. E. D. Chidsey. “Electrocatalytic O2 reduction by covalently immobilized mononuclear copper (I) complexes: Evidence for a binuclear Cu2O2 intermediate,” J. Am. Chem. Soc. 133, 3696-3699, doi:10.1021/ja106338h (2011).
- Lowe, R. D., M. A. Pellow, T. D. P. Stack, and C. E. D Chidsey. “Deposition of dense siloxane monolayers from water and trimethoxyorganosilane vapor,” Langmuir (submitted for publication, 2011).
- Pearson, D. M. and R. M. Waymouth. “Mechanistic studies of the oxidative dehydrogenation of methanol using a cationic Pd complex.” Organometallics, 28 (13), 3896-3900, doi:10.1021/om900217s (2009).
- Nakazawa, J. and T. D. P. Stack. “Controlled loadings in a mesoporous material: Click-on silica.” J. Am. Chem. Soc., Vol. 130, No. 44, pp. 14360-14365, doi:10.1021/ja804237b (2008).
- McCrory, C. C. L., X. Ottenwaelder, T. D. P. Stack, and C. E. D. Chidsey. ” Kinetic and mechanistic studies of the electrocatalytic reduction of O2 to H2O with mononuclear Cu complexes of substituted 1, 10-phenanthrolines.” J. Phys. Chem. A Vol. 111, No. 49, 12641-12650, doi:10.1021/jp076106z (2007).
- Conley, N. R., L. A. Labois, D. M. Pearson, D. M., C. McCrory, and R. M. Waymouth. “Aerobic alcohol oxidation with cationic palladium complexes: Insights into catalyst design and decomposition.” Organometallics, Vol. 26, No. 23, pp. 5447-5453, doi:10.1021/om700492n (2007).
- Okamoto, M. L. Senatore, M. M. Ling, A. B. Mallik, M. L. Tang, and Z. Bao. “Synthesis, characterization, and field-effect transistor performance of pentacene derivatives.” Advanced Materials, 19, No. 20, pp. 3381-3384, doi:10.1002/adma.200700298 (2007).
- Okamoto, M. L. and Z. Bao. “Synthesis of Solution-Soluble Pentacene-Containing Conjugated Copolymers.” American Chemical Society, Vol. 129, No. 34, pp. 10308-10309, doi:10.1021/ja0725403 (2007).
- Sista, S., Y. Yao, Y. Yang, M. L. Tang, and Z. Bao. “Enhancement in open circuit voltage through a cascade-type energy band structure.” Applied Physics Letters, Vol. 91, No. 2, 223508, doi:10.1063/1.2817935 (2007).
- Mayer, A. C., S. R. Scully, B. E. Hardin, M. W. Rowell, and M. D. McGehee. “Polymer-based solar cells.” Materials Today, Vol. 10, No. 11, pp. 28-33, doi:10.1016/S1369-7021(07)70276-6 (2007).
- Scully, S. R., P. B. Armstrong, C. Edder, J. M .J. Frechet, and M. D. McGehee. “Long-range resonant energy transfer for enhanced exciton harvesting for organic solar cells.” Advanced Materials, Vol. 19, No. 19, pp. 2961-2966, doi:10.1002/adma.200700917 (2007).
- Scully, S. R. and M. D. McGehee. “Effects of optical interference and energy transfer on exciton diffusion length measurements in organic semiconductors.” Applied Physics, Vol. 100, No. 3, 034907, doi:10.1063/1.2226687 (2006).
Metal Oxide Nanotubes and Photo-Excitation Effects: New Approaches for Low-to-Intermediate Temperature Solid Oxide Fuel Cells
- Shandalov, M. and P.C. McIntyre, “Size-dependent polymorphism in HfO2 nanotubes and nanoscale thin films.” Journal of Applied Physics, 106 (8), 084322-084322-5 doi:10.1063/1.3243077 (2009).
- Tsuchiya, M., V. Shutthandan, M. Engelhard, and S. Ramanathan. “Direct measurement of oxygen incorporation into thin film oxides at room temperature under photon irradiation.” Applied Physics Letters, Vol. 93, 263109, doi:10.1063/1.3058691(2008)
- Karthikeyan, A., M. Tsuchiya, and S. Ramanathan. “Apatite-phase synthesis from interdiffusion in doped CeO2-SiO2 thin film superlattices and in-situ conductivity studies.” Electrochemical and Solid State Letters, Vol. 11, K101 (2008).
- Tsuchiya M. and S. Ramanathan. “Enhanced grain growth in yttria-doped zirconia thin film structures under photon irradiation.” Philosophical Magazine Letters, Vol. 88, No. 8, pp. 583-590, doi:10.1080/09500830802322178 (2008).
- Tsuchiya M. and S. Ramanathan. “Ultra-thin Y-doped zirconia membranes synthesized under photon irradiation: Structure evolution and high temperature electrochemical transport studies.” Electrochemical Society Transactions, Vol. 11, 9 (2008).
- Synthesis and interfacial phenomena in ultra-thin ytrria-doped zirconia films grown by alloy oxidation under photon irradiation, M. Tsuchiya and S. Ramanathan, Applied Physics Letters, 92, 033107 (2008)
- Effect of photon irradiation on structure of yttria-doped zirconia thin films grown on semiconductor substrates, M. Tsuchiya and S. Ramanathan, Applied Physics Letters, 91, 253104 (2007)
Nanoscale Architectural Engineering for High Performance Solid Oxide Fuel Cells
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Cuicci, F., W. C. Chueh, D. G. Goodwin, and S. M. Haile. “Surface reaction and transport in mixed conductors with electrochemically-active surfaces: A 2-D numerical study of ceria,” Phys. Chem. Chem. Phys. 13, 2121-2135, doi:10.1039/C0CP01219J (2011).
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Chueh, W. C., Y. Hao, and S. M. Haile. “High electrochemical activity of the oxide phase in model Ceria-Pt and Ceria-Ni composite anodes,” (submitted, 2011).
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Usiskin, R. E., R. Wang, and S. M. Haile. “Electronic behavior of Ba0.5Sr0.5Co0.8Fe0.2O3-δ and SrCo0.9Nb0.1O3-δ,” (submitted, 2011).
- E. C. Brown, S. K. Wilke, D. A. Boyd, D. G. Goodwin and S. M. Haile. “Polymer sphere lithography for solid oxide fuel cells: A route to functional, well-defined electrode structures.” J. Mat. Chem., 20, 2190-2196, doi:10.1039/b920973e (2010).
- W. C. Chueh and S. M. Haile. “Electrochemical studies of capacitance in cerium oxide thin films and its relationship to anionic and electronic defect densities.” Phys. Chem. Chem. Phys., 11 (37), 8144 – 8148, doi:10.1039/b910903j (2009).
Nature-Inspired Solid-State Electrocatalysts: The Oxidation of Water and the Reduction of CO2 to Fuels
- Kuhl, K. P., E. R. Cave, D. N. Abram, and T. F. Jaramillo. "New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces." Energy & Environmental Science, 5, 7050-7059 (2012).
- Ng J, Y. Gorlin, and T. Jaramillo. "Nanostructured particles of manganese oxide for ORR in alkalinebased fuel cells" (in preparation, 2012).
- Cave, E. R, K. P. Kuhl, D. N. Abram, and T. F. Jaramillo. "Electrochemical Reduction of Carbon Dioxide on Gold", (in preparation, 2012).
- Abram, D.N.; K. P. Kuhl, E. R. Cave, and T. F. Jaramillo. "Electrochemical Reduction of CO2 on Platinum and Polyaniline-Coated Platinum and Modification of Product Distribution" (in preparation, 2012).
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